Reversible lithium insertion and copper extrusion in layered oxysulfides.

نویسندگان

  • Oliver J Rutt
  • Gareth R Williams
  • Simon J Clarke
چکیده

All of the copper in the layered oxysulfides Sr2MnO2Cu1.5S2 and Sr2MnO2CU3.5S3 may be extruded as the element and the copper ions replaced quasi-reversibly by lithium ions in reductive topotactic ion exchange reactions; dramatic changes in magnetic properties result.

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عنوان ژورنال:
  • Chemical communications

دوره 27  شماره 

صفحات  -

تاریخ انتشار 2006